Photochemical Cyclization of Allylated Anisole and N‐Alkyl Aniline Derivatives. Preliminary communication
作者:
Ursula Koch‐Pomeranz,
Hans‐Jürgen Hansen,
Hans Schmid,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1975)
卷期:
Volume 58,
issue 1
页码: 178-182
ISSN:0018-019X
年代: 1975
DOI:10.1002/hlca.19750580122
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
AbstractThe allyl anisole derivatives1, d2‐1,3,5and7(Scheme 1), on exposure to UV. light in benzene, acetone or methanol solution, cyclize to yield the corresponding cyclopropyl anisole derivatives2, d2‐2,cis‐ andtrans‐4, 6and8, respectively. Under the above conditions the N, N‐dialkyl‐2‐allyl anilines9,10and11give similar results (Scheme 2). On the other hand, N‐alkyl‐2‐allyl anilines (15and19,Scheme 3) are transformed by UV. light in cyclohexane or benzene solution into 2‐methyl‐indolines (16and20, resp.), whereas in methanol solution the corresponding 2′‐methoxy compounds18and21are formed in addit
点击下载:
PDF
(254KB)
返 回