首页   按分类浏览 期刊浏览 卷期浏览 Photochemical Cyclization of Allylated Anisole and N‐Alkyl Aniline Derivatives. Prelimi...
Photochemical Cyclization of Allylated Anisole and N‐Alkyl Aniline Derivatives. Preliminary communication

 

作者: Ursula Koch‐Pomeranz,   Hans‐Jürgen Hansen,   Hans Schmid,  

 

期刊: Helvetica Chimica Acta  (WILEY Available online 1975)
卷期: Volume 58, issue 1  

页码: 178-182

 

ISSN:0018-019X

 

年代: 1975

 

DOI:10.1002/hlca.19750580122

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractThe allyl anisole derivatives1, d2‐1,3,5and7(Scheme 1), on exposure to UV. light in benzene, acetone or methanol solution, cyclize to yield the corresponding cyclopropyl anisole derivatives2, d2‐2,cis‐ andtrans‐4, 6and8, respectively. Under the above conditions the N, N‐dialkyl‐2‐allyl anilines9,10and11give similar results (Scheme 2). On the other hand, N‐alkyl‐2‐allyl anilines (15and19,Scheme 3) are transformed by UV. light in cyclohexane or benzene solution into 2‐methyl‐indolines (16and20, resp.), whereas in methanol solution the corresponding 2′‐methoxy compounds18and21are formed in addit

 

点击下载:  PDF (254KB)



返 回