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Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

 

作者: Kimihisa Yamamoto,   Toshio Asada,   Hiroyuki Nishide,   Eishun Tsuchida,  

 

期刊: Polymers for Advanced Technologies  （WILEY Available online 1990）
卷期: Volume 1, issue 3‐4  

页码: 207-210

 

ISSN:1042-7147

 

年代: 1990

 

DOI:10.1002/pat.1990.220010303

 

出版商: John Wiley&Sons, Ltd.

 

关键词: Electro‐polymerization;Cyclohexadiene;Poly(cyclohexene);Cationic oxidation;Poly(phenylene)

 

数据来源: WILEY

 

摘要:

Abstract1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR,1H‐ and13C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a p

 

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