The Ordering of Localized Electron Pairs in Mixed-Valence Crystals
作者:
L.A. Manakova,
S.P. Ionov,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1982)
卷期:
Volume 2,
issue 3
页码: 237-259
ISSN:0144-235X
年代: 1982
DOI:10.1080/01442358209353336
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The aim of this article is to describe the factors that determine the types of ground states in crystals with localized electron pairs, or bipolarons. We consider the concentration of the electron pairs and parameters describing the lattice polarization due to the bipolaron-phonon interaction, together with parameters for the possible ground states. All the parameters and the bipolaron concentration must be self-consistently related. The conditions that favour the disordered and superconducting states, and the charge-ordered states, of such crystals are presented.
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