Crosslinking of latex polymers
作者:
Valentina I. Yeliseeva,
期刊:
British Polymer Journal
(WILEY Available online 1975)
卷期:
Volume 7,
issue 1
页码: 33-49
ISSN:0007-1641
年代: 1975
DOI:10.1002/pi.4980070105
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractThe physicomechanical properties and processes of thermal crosslinking of latex acrylic polymer films containing functional groups of different chemical nature were studied. Improvement of properties characteristic of latex copolymers containing methylolamide groups is explained by orientated location of hydrophilic groups on the surface of latex particles during emulsion copolymerisation, that, in its turn, leads to a more ordered arrangement of macrochains. An optimum content of methylolamide groups as regards crosslinking processes was established and explained by steric location of these groups on the surfaces of latex particles. A similar optimum is not observed for crosslinking by watersoluble resin of latex copolymers containing groups of hydrophobic glycidylmethacrylate.
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