Elongational flow behavior of ABS polymer melts
作者:
L. Li,
T. Masuda,
M. Takahashi,
期刊:
Journal of Rheology
(AIP Available online 1990)
卷期:
Volume 34,
issue 1
页码: 103-116
ISSN:0148-6055
年代: 1990
DOI:10.1122/1.550112
出版商: The Society of Rheology
关键词: Elongational viscosity;Strain rate dependence of elongational viscosity;ABS polymer melt;Uniaxial extensional rheometer;MELTS;ELONGATION;VISCOSITY;RUBBERS;STRAINS;COPOLYMERS;ACRYLONITRILE;POLYSTYRENE
数据来源: AIP
摘要:
Elongational flow behavior of ABS polymer melts with various rubber‐particle contents was investigated by using a Meissner‐type uniaxial extensional rheometer. The effects of strain rate and rubber particles on the elongational behavior are discussed. A linear viscoelastic behavior was observed at sufficiently low strain rates ε̇. The dependence of linear elongational viscosity η+E(t) on particle content is weak at short times but becomes stronger with time. Two types of mechanisms which cause the deviation of nonlinear viscosity function η+E(t,ε̇) from η+E(t) at high strain rates in the short and long time regions were proposed. These deviations are respectively attributed to a volumetric resistance against the radial deformation of the samples because of the existence of particles, and an extension of matrix polymers in an elongational flow field.
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