Structure-Performance Characteristics of Ethylene-Propylene Copolymers in Oil
作者:
I.D. Rubin,
A.J. Stipanovic,
A. Sen,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue sup1
页码: 75-83
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108054386
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A study was made of the viscosities of three ethylene-propylene copolymers in a naphthenic base oil. Two of the copolymers contained, respectively, 60 and 70 mol% ethylene and were amorphous while the third had 80 mol% ethylene and was partially crystalline. At room temperature, the solutions of both amorphous and partially crystalline copolymers were Newtonian. At low temperatures, the solution of the partially crystalline copolymer became non-Newtonian and gave viscosity values which were much lower than expected on the basis of molecular weight. These results are interpreted in terms of formation of ordered domains or aggregates in the solutions of the partially crystalline copolymers at low temperatures.
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