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Structure-Performance Characteristics of Ethylene-Propylene Copolymers in Oil

 

作者: I.D. Rubin,   A.J. Stipanovic,   A. Sen,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1991)
卷期: Volume 28, issue sup1  

页码: 75-83

 

ISSN:0022-233X

 

年代: 1991

 

DOI:10.1080/00222339108054386

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A study was made of the viscosities of three ethylene-propylene copolymers in a naphthenic base oil. Two of the copolymers contained, respectively, 60 and 70 mol% ethylene and were amorphous while the third had 80 mol% ethylene and was partially crystalline. At room temperature, the solutions of both amorphous and partially crystalline copolymers were Newtonian. At low temperatures, the solution of the partially crystalline copolymer became non-Newtonian and gave viscosity values which were much lower than expected on the basis of molecular weight. These results are interpreted in terms of formation of ordered domains or aggregates in the solutions of the partially crystalline copolymers at low temperatures.

 

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