Defect interactions, statistical thermodynamic and electronic transport in ionic nonstoichiometric oxides
作者:
R. Tetot,
G. Boureau,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1995)
卷期:
Volume 137,
issue 1-4
页码: 239-246
ISSN:1042-0150
年代: 1995
DOI:10.1080/10420159508222728
出版商: Taylor & Francis Group
关键词: nonstoichimetry;binary metal oxides;defect structure;Monte Carlo simulations;Statistical Thermodynamics
数据来源: Taylor
摘要:
In this paper, we discuss the effects of the defect interactions on the thermodynamic properties and electronic transport of nonstoichiometric oxides. We first show that two limited thermodynamic behaviours can be distinguished depending on whether the oxide has a metallic type electronic conduction or a hopping electronic conduction. In the first case, the interactions are expected to be short ranged because of the screening of the conduction electrons, while they are Coulombic in the second case. This paper is limited to this last case, exemplified mainly by M1−xO(M=Co, Mn,…) cubic oxides.
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