Defect density evolution and steady rheological behaviors of liquid‐crystalline polymers
作者:
Kwang Man Kim,
Hansol Cho,
In Jae Chung,
期刊:
Journal of Rheology
(AIP Available online 1994)
卷期:
Volume 38,
issue 5
页码: 1271-1283
ISSN:0148-6055
年代: 1994
DOI:10.1122/1.550543
出版商: The Society of Rheology
关键词: LIQUID CRYSTALS;POLYMERS;RHEOLOGY;SHEAR FLOW;DOMAIN STRUCTURE;DENSITY;DEFECTS;SCALING LAWS;SHEAR PROPERTIES;TEXTURE;VISCOSITY
数据来源: AIP
摘要:
In a polydomain model for textured liquid‐crystalline polymers, domain shrinkage and texture coarsening at low shear rates are considered to be driven by the deviations of defect densityLfrom the initial (L0) and steady (Ls) states, respectively. The densities ofL0andLscorrespond to the average domain sizes ofa0andasat each state. The introduction ofL0into the Larson–Doi defect density evolution equation provides a limit of texture length scale, eliminating the indefinite coarsening of texture. Then, the defect density evolution is refreshed in each case of the steady state, shear inception, and shear cessation. With the inclusion ofL0, the shear thinning behavior of a steady‐state viscosity curve can be developed in Onogi–Asada’s region I as well as the Newtonian plateau behavior in region II. Moreover, another Newtonian plateau region over very low shear rates, called ‘‘region 0,’’ can be predicted when smaller domains are considered to be isotropically distributed at the initial state.
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