The extraction behavior of Zn(II), Cd(II), Hg(II), Au(III), and Tl(III) has been studied at different HCl molarities in some commercially available liquid anion exchangers. The effect of such variables as the type of amine, molarity of HCl, amine concentration, and organic diluent on extraction has been explored to suggest the best conditions of separation of Hg(II) from Zn(II), Cd(II), Au(III), and Tl(III).