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Dielectric Study and Helical Pitch Measurements on a New Antiferroelectric Liquid Crystal

 

作者: F. Bibonne,   J.P. Parneix,   N. Isaert,   G. Joly,   H.T. Nguyen,   A. Bouchta,   C. Destrade,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 263, issue 1  

页码: 27-35

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508033567

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The dielectric dispersion in the ferroelecric and antiferroelectric phases of a new liquid crystal (S)-4-(1-methylheptyloxycarbonyl)-phenyl 4-(4-dodecyloxybenzoyloxy)benzoate has been investigated in the frequency range from 10 Hz to 10 MHz. The behaviour of the soft mode in SmA and the Goldstone mode in SmC* have been determined. Two dielectric relaxations have been recognized in the antiferroelectric SmC*Aphase : the first one between 5 kHz and 50 kHz and the second one, also observable in the ferrielectric SmC*FIphase, around 1 MHz. In SmC*FI, a drastic change in the behaviour of the low frequency response has been found depending on whether the sample was heated or cooled. A sign reversal of the helical pitch has been determined inside the SmC*FIphase, leading to low pitch values of opposite sign in SmC*Aand SmC*.

 

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