Dielectric Study and Helical Pitch Measurements on a New Antiferroelectric Liquid Crystal
作者:
F. Bibonne,
J.P. Parneix,
N. Isaert,
G. Joly,
H.T. Nguyen,
A. Bouchta,
C. Destrade,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 263,
issue 1
页码: 27-35
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033567
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The dielectric dispersion in the ferroelecric and antiferroelectric phases of a new liquid crystal (S)-4-(1-methylheptyloxycarbonyl)-phenyl 4-(4-dodecyloxybenzoyloxy)benzoate has been investigated in the frequency range from 10 Hz to 10 MHz. The behaviour of the soft mode in SmA and the Goldstone mode in SmC* have been determined. Two dielectric relaxations have been recognized in the antiferroelectric SmC*Aphase : the first one between 5 kHz and 50 kHz and the second one, also observable in the ferrielectric SmC*FIphase, around 1 MHz. In SmC*FI, a drastic change in the behaviour of the low frequency response has been found depending on whether the sample was heated or cooled. A sign reversal of the helical pitch has been determined inside the SmC*FIphase, leading to low pitch values of opposite sign in SmC*Aand SmC*.
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