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Potential energy effects on the sound speed in liquids

 

作者: Bruce Hartmann,  

 

期刊: The Journal of the Acoustical Society of America  (AIP Available online 1979)
卷期: Volume 65, issue 6  

页码: 1392-1396

 

ISSN:0001-4966

 

年代: 1979

 

DOI:10.1121/1.382924

 

出版商: Acoustical Society of America

 

数据来源: AIP

 

摘要:

Sound speed in liquids is calculated in terms of Mie potential parameters with the assumption that the intermolecular potential energy is the dominant factor. Using this simple model, it is shown that Beyer’s parameter of nonlinearity, Rao’s exponent, and the Gruneisen parameter are all simply related to each other. Liquids obey a law of corresponding states in terms of reduced variablesc2/U0andV/V0, wherecis sound speed,U0is the heat of vaporization,Vis specific volume, andV0specific volume at absolute zero temperature. To a first approximation, the parameter of nonlinearity is shown to be a linear function of reciprocal sound speed, and the calculated results are in reasonably good agreement with the empirical result noted by Ballou.

 

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