Recent Advances in Site-specific Natural Isotope Fractionation Studied by Nuclear Magnetic Resonance
作者:
GérardJ. Martin,
期刊:
Isotopes in Environmental and Health Studies
(Taylor Available online 1998)
卷期:
Volume 34,
issue 3
页码: 233-243
ISSN:1025-6016
年代: 1998
DOI:10.1080/10256019808234056
出版商: Taylor & Francis Group
关键词: Carbon 13 fractionation;deuterium;environmental and mechanistic effects;glycerol;nicotine;vanillin
数据来源: Taylor
摘要:
Site-specific Natural Isotopic Fractionation of hydrogen and carbon in nicotine, glycerol and vanillin was studied by NMR spectroscopy (SNIF-NMR) in order to point out specific mechanistic and environmental effects. Several products (cellulose, sugars, acids, nicotine) isolated from tobacco leaves present related carbon and nitrogen fractionation profiles. In nicotine, it is possible to measure eleven site-specific isotope ratios (D/H)iwhich give useful information about the climate of the region of production. The origin of glycerol in fermented beverages can be determined by2H and13C-NMR, and the botanical origin of triglycerides can also be checked in the same way.
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