THE USE OF SOFT DONOR LIGANDS, 4-BENZOYL-2,4-DIHYDRO-5- METHYL-2-PHENYL-3H-PYRAZOL-3-THIONE AND 4,7-DIPHENYL-UO- PHENANTHROLINE, FOR IMPROVED SEPARATION OF TRIVALENT AMERICIUM AND EUROPIUM
作者:
D. D. Ensor,
G. D. Jarvinen,
B. F. Smith,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1988)
卷期:
Volume 6,
issue 3
页码: 439-445
ISSN:0736-6299
年代: 1988
DOI:10.1080/07366298808917948
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The extraction of Am(ITI) and Eu(III) from aqueous 0.1 M NaClO4 using a mixture of 4-benzoyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-thione (HBMPPT) and 4,7-diphenyl-l,10-phenanthroline (DPPHEN) was studied. Individually, neither the HBMPPT nor the DPPHEN in toluene showed any extraction capabilities for Am(III) or Eu(III) under the experimental conditions used in this study. Combination of the two ligands, however, yielded a synergistic system which showed a strong preference for Am(III) over Eu(III). Slope analysis indicated that the extracted species took the form M(BMPPT)3(DPPHEN) for both metal ions studied. The separation factor DAm/DEu was 190 at pH = 3.7, [HBMPPT] = 3.0 x 10-2, and [DPPHEN] = 2.7 x 10-3.
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