The enantiomeric composition of triadimenol produced during metabolism of triadimefon by fungi. Part I: Influence of dose and time of incubation
作者:
Adrian H. B. Deas,
Terence Clark,
Geoffrey A. Carter,
期刊:
Pesticide Science
(WILEY Available online 1984)
卷期:
Volume 15,
issue 1
页码: 63-70
ISSN:0031-613X
年代: 1984
DOI:10.1002/ps.2780150110
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractBotrytis cinerea, grown in shake culture in a liquid nutrient medium containing different amounts of triadimefon (4–40 mg litre−1), produced triadimenol as the sole major metabolite. Analysis by gas‐liquid chromatography (g.l.c.) showed the presence of (1R,2S) and (1S,2S)‐triadimenol, but no (1S,2R) or (1R,2R)‐enantiomer. The proportion of (1R,2S) to (1S,2S)‐triadimenol decreased over the period 6 to 168 h and with increased amounts of applied triadimefon. The implications of these patterns of metabolism are discussed in terms of overall fungitoxicity, the stereospecificity of the reduction process and the shortcomings of conventional, non‐chiral analysis of diastereoisomers by g.l.c. for assessing the sensitivity of fungi to such fungicides a
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