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Theoretical calculations of the Rydberg spectra of ArH

 

作者: G. Theodorakopoulos,   I.D. Petsalakis,   R.J. Buenker,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 71, issue 5  

页码: 1055-1062

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000102311

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A series of multireference (MRD-CI) calculations are presented for the electronic states of ArH correlating with the atomic limits up to Ar(1S) + H* (n= 3), in order to provide transition energies corresponding to the possible Rydberg spectra of ArH. The computed transition energies for several2Π → A2∑+transitions are found to be in good agreement with experimentalT0values, with discrepancies that in every case are smaller than 0·1 eV.

 

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