The Synthesis of 1,2-Diarylpropane-1,3-Diols via the Ivanoff Reaction
作者:
ArthurJ. Nonni,
CarltonW. Dence,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1982)
卷期:
Volume 2,
issue 2
页码: 161-168
ISSN:0277-3813
年代: 1982
DOI:10.1080/02773818208085127
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The synthesis of two β-1 lignol dimers, 1,2-bis-(4-hydroxy-3-methoxyphenyl)-i,3-propanediol (Via) and l-(3-ethoxy-4-hydroxyphenyl)-2-(4-hydroxy-3-methoxyphenyl)-1,3-propanediol (VIb) was performed using the Ivan off Reaction in the key synthetic step. The erythro forms of Via and b were isolated as crystalline solids in yields of approximately 15%, while the threo isomers were obtained as oils. The ratio of threo: erythro isomers was approximately 3:1.
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