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Improved Flory Formula for the Excess Free Energy of a Binary Liquid Mixture

 

作者: A.B. Bhatia,   W.H. Young,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1984)
卷期: Volume 14, issue 1  

页码: 47-52

 

ISSN:0031-9104

 

年代: 1984

 

DOI:10.1080/00319108408080794

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A simple model for the free energy of mixing of a binary fluid is proposed using hard spheres as a reference system and a tail interaction between the unlike atoms. The model, firstly, provides an interpretation and rationale for the interchange energy parameterwand its temperature dependence occurring in the Flory formula and for a number of other current ideas. Secondly, it leads to a formula which appears to be a suitable next step in the refinement of the Flory model.

 

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