Improved Flory Formula for the Excess Free Energy of a Binary Liquid Mixture
作者:
A.B. Bhatia,
W.H. Young,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1984)
卷期:
Volume 14,
issue 1
页码: 47-52
ISSN:0031-9104
年代: 1984
DOI:10.1080/00319108408080794
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A simple model for the free energy of mixing of a binary fluid is proposed using hard spheres as a reference system and a tail interaction between the unlike atoms. The model, firstly, provides an interpretation and rationale for the interchange energy parameterwand its temperature dependence occurring in the Flory formula and for a number of other current ideas. Secondly, it leads to a formula which appears to be a suitable next step in the refinement of the Flory model.
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