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On the Use of Grand Ensembles in Statistical Mechanics: A New Derivation of Saha's Formula

 

作者: D. ter Haar,  

 

期刊: American Journal of Physics  （AIP Available online 1955）
卷期: Volume 23, issue 6  

页码: 326-331

 

ISSN:0002-9505

 

年代: 1955

 

DOI:10.1119/1.1934002

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

The advantages of using the method of the grand ensembles are discussed. As a special case Saha's formula for dissociation equilibria is derived using the method of the quantum-mechanical canonical grand ensembles. One of the advantages in this case is that it is possible at each step to take stock of the simplifying assumptions made during the derivation.

 

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