Raman Intensity of thevC=OBand in Hydrogen Bonded Complexes Involving Ethylformate and Phenol Derivatives
作者:
L. Vanderheyden,
R. Vandenbrande,
Th. Zeegers-Huyskens,
期刊:
Spectroscopy Letters
(Taylor Available online 1989)
卷期:
Volume 22,
issue 4
页码: 451-459
ISSN:0038-7010
年代: 1989
DOI:10.1080/00387018908053894
出版商: Taylor & Francis Group
关键词: Raman spectroscopy;hydrogen bonds;ethylformate
数据来源: Taylor
摘要:
The hydrogen bonded complexes between carbonyl bases and hydroxylic derivatives have been extensively studied by infrared spectrometry; by comparison very little Raman data have been reported in the literature. Some qualitative measurements on thevC=Oband of acetone dissolved in water-tetrachloride mixtures have been performed by Singurel1. Quantitative data on the absolute Raman intensity have been obtained for complexes involving cyclohexanone2, acetone, acetophenone3and methylacetate4. For these systems, hydrogen bond formation brings about a moderate intensity enhancement of thevC=Oband. In this work the Raman intensity of thevC=Oband of ethylformate (EtFo) complexed with phenol derivatives is investigated.
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