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Self Diffusion of Diastereomeric Complexes

 

作者: M. Geringer,   H. Sterk,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1992）
卷期: Volume 25, issue 5  

页码: 619-625

 

ISSN:0038-7010

 

年代: 1992

 

DOI:10.1080/00387019208020696

 

出版商: Taylor & Francis Group

 

关键词: Pulse gradient techniques;Selfdiffusion constants;diastereomeric complexes

 

数据来源: Taylor

 

摘要:

For systems in which a chiral substrate and a different chiral metal chelate are forming a diastereomeric complex it is often not possible to determine the complex formation constant using chemical shift data only. It is shown that an unambigu - ous determination of complex formation constants is possible by combining data obtained from chemical shift measurements and self diffusion measurements.

 

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