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Carbocationic Polymerization in the Presence of Sterically Hindered Bases. X. Summary and Quantitative Kinetic Confirmation of the Mechanism

 

作者: J.P. Kennedy,   T. Kelen,   S.C. Guhaniyogi,   R.T. Chou,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1982)
卷期: Volume 18, issue 1  

页码: 129-152

 

ISSN:0022-233X

 

年代: 1982

 

DOI:10.1080/00222338208056663

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The findings presented in the preceding articles of this special issue have been organized, analyzed, and summarized. Commonalities among the various polymerization systems investigated in detail have been identified and phenomena of general validity were found. Increased insight into the mechanism of initiation and chain transfer processes led to the development of a comprehensive kinetic model which was used to describe the assembled data. Excellent quantitative agreement between experimental and calculated data indicates the validity of the mechanistic/kinetic model developed from chemical principles in regard to fast-initiated nonstationary carbocationic polymerizations in the absence and presence of proton traps.

 

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