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The temperature dependence of the νs(OH) frequency of self-associated methanol in solution

 

作者: J. Bournay,   G.N. Robertson,  

 

期刊: Molecular Physics  （Taylor Available online 1980）
卷期: Volume 39, issue 1  

页码: 163-174

 

ISSN:0026-8976

 

年代: 1980

 

DOI:10.1080/00268978000100131

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The first momentM1(H) of thevs(OH) absorption band of self-associated CD3OH in freon 11 and the corresponding first momentM1(D) of self-associated CH3OD have been measured at 10 K intervals between 160 K and 280 K. The regression of the moments on coth (ħω2/2kT) is close to linear, with correlation coefficients of 0·998 for H and 0·999 for D. The ratioM1(H)/M1(D) is independent of temperature.

 

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