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TBAF‐Mediated Dimerization Reaction of β,γ‐Unsaturated Arylketones

 

作者: Meng‐Yang Chang,   Chin‐Yi Hung,   Shiang‐Tsern Lin,  

 

期刊: Journal of the Chinese Chemical Society  （WILEY Available online 2008）
卷期: Volume 55, issue 1  

页码: 9-12

 

ISSN:0009-4536

 

年代: 2008

 

DOI:10.1002/jccs.200800003

 

出版商: WILEY‐VCH Verlag

 

关键词: TBAF;Dimerization;β,γ‐Unsaturated arylketones

 

数据来源: WILEY

 

摘要:

AbstractA simple and high‐yield method for the synthesis of several 1,5‐diaryl‐1,5‐dicarbonyl compounds has been established starting from TBAF‐mediated isomerization and dimerization reaction of β,γ‐unsaturated arylketones (allyl arylketones) with mono‐, di‐, and tri‐methoxy groups, which is derived from allylation of commercially available different benzaldehydes and followed by oxidation of the resulting

 

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