Substitutional carbon inSi1−yCyalloys as measured with infrared absorption and Raman spectroscopy
作者:
M. Mele´ndez-Lira,
J. Mene´ndez,
K. M. Kramer,
M. O. Thompson,
N. Cave,
R. Liu,
J. W. Christiansen,
N. D. Theodore,
J. J. Candelaria,
期刊:
Journal of Applied Physics
(AIP Available online 1997)
卷期:
Volume 82,
issue 9
页码: 4246-4252
ISSN:0021-8979
年代: 1997
DOI:10.1063/1.366231
出版商: AIP
数据来源: AIP
摘要:
We present a study of the infrared absorption and Raman scattering intensity of the local carbon mode inSi1−yCyalloys grown by direct carbon implantation followed by different recrystallization procedures. For the case of laser-induced recrystallization, the integrated infrared absorbances are found to agree with an extrapolation of the calibration curve previously determined for very low substitutional carbon concentrations in Si. We argue that this finding provides strong evidence for the achievement of nearly perfect substitutionality in laser-recrystallized films, even though their carbon concentrations are three orders of magnitude beyond the solubility limit of carbon in Si. This conclusion is found to be consistent with measurements of the intensity of defect-induced Si Raman scattering relative to the Raman intensity of the local carbon mode. The Raman intensity of the local carbon mode at605 cm−1relative to the first-order Si Raman line at521 cm−1provides an ideal spectroscopic tool for the determination of substitutional carbon concentrations. By correlating Raman and infrared measurements, we find that for laser excitation at 488 nm the intensity ratio is given byI605/I521=(3.7±0.2)ysub.©1997 American Institute of Physics.
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