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Elastic Constants ofD2OIce and Variation of Intermolecular Forces on Deuteration

 

作者: U. Mitzdorf,   D. Helmreich,  

 

期刊: The Journal of the Acoustical Society of America  (AIP Available online 1971)
卷期: Volume 49, issue 3B  

页码: 723-728

 

ISSN:0001-4966

 

年代: 1971

 

DOI:10.1121/1.1912408

 

出版商: Acoustical Society of America

 

数据来源: AIP

 

摘要:

The elastic constants ofD2Oice have been measured between 0° and −140°C. From these data and the elastic constants ofH2Oice, the molecular force constants—Kfor change of bond length andGfor change of 0⋯0⋯0 angle—have been calculated.KandGshow a similar temperature dependence as the elastic constants; their absolute values enlarge on deuteration. For comparison, values ofKandGcalculated from infrared data are given.

 

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