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Two Stabilized Calix[6]Cryptand Stereo Isomers used as Stationary Phases for Capillary Gas Chromatography

 

作者: Jun Xing,   Jiansen Li,   Caiying Wu,   Yuanyin Chen,   Xueran Lu,   Huiming Han,  

 

期刊: Analytical Letters  (Taylor Available online 1999)
卷期: Volume 32, issue 15  

页码: 3071-3081

 

ISSN:0003-2719

 

年代: 1999

 

DOI:10.1080/00032719908543028

 

出版商: Taylor & Francis Group

 

关键词: Calix[6]arene;cryptand;stationary phases;capillary gas chromatography

 

数据来源: Taylor

 

摘要:

A couple of stabilized calix[6]cryptand steroisomers were synthesized by capping 1,3,5-trimethoxy-p-tert-butylcalix[6]arene with 1,1,1-tri(tosyloxyethoxyethoxymethyl)-propane and used as stationary phases for capillary gas chromatography. Their chromatographic characteristics and separation mechanism for aromatic positional isomers and polycyclic aromatic hydrocarbons are discussed.

 

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