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Rates of extraction of mercaptan sulfur from pentane by caustic solution

 

作者: N. L. Carr,   Y. T. Shah,  

 

期刊: The Canadian Journal of Chemical Engineering  (WILEY Available online 1979)
卷期: Volume 57, issue 1  

页码: 35-41

 

ISSN:0008-4034

 

年代: 1979

 

DOI:10.1002/cjce.5450570106

 

出版商: Wiley Subscription Services, Inc., A Wiley Company

 

数据来源: WILEY

 

摘要:

AbstractThe interphase rate process for the extraction of mercaptan sulfur from n‐pentane with a 10% caustic solution is examined. The system represents a case of mass transfer with an equilibrium chemical reaction occurring in one phase. Experimental studies were made with both a continuous flow stirred tank reactor (CFSTR) and an annular flow jet reactor (AFJR). The interphase volumetric mass transfer coefficient (KLa) was derived based on Olander's theory. The KLa data for each contactor was found to be a function of the power input per unit volume. The AFJR exhibited higher KLa values and equilibration of mercaptan sulfur was achieved in about three millisecond

 

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