A Theoretical Model for Determining Oscillator Strength Using a Non-spherical Molecular Cavity and Measurement of the He-Ne Laser Light Absorption Coefficient in Solutions
作者:
Manoj Johri,
GajendraK. Johri,
J.A. Roberts,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 23,
issue 2
页码: 101-107
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108030639
出版商: Taylor & Francis Group
关键词: Light absorption;ion-solvent interaction
数据来源: Taylor
摘要:
An alternative theoretical formulation for determining oscillator strength using a non-spherical molecular cavity is developed and this model correlated with experimental measurements made using non-resonant scattering of a He-Ne laser beam incident upon select aqueous ionic concentrations of NaCl. The light beam was transmitted through each sample and measurements made, at room temperature, on the transmitted light to determine the shape factor. The shape factor was estimated to be 0.30 from the results of this experiment. The nature of the ion-solvent interaction was obtained from the dielectric decrement.
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