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Elastic constants of nonmetamict zirconium silicate

 

作者: H. O¨zkan,   L. Cartz,   J. C. Jamieson,  

 

期刊: Journal of Applied Physics  (AIP Available online 1974)
卷期: Volume 45, issue 2  

页码: 556-562

 

ISSN:0021-8979

 

年代: 1974

 

DOI:10.1063/1.1663283

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Two independent reports in the literature for the elastic constants of zircon (zirconium silicate) are in disagreement by an order of magnitude and are reported without specifying the conditions of the mineralogical specimens. However, natural zircon crystals frequently contain uranium and thorium atoms as an impurity so that zircon can exist in a metamict (radiation damaged) condition. A redetermination of the elastic constants has been carried out on small synthetic crystals and on high‐purity natural single crystals of nonmetamict zircon of lattice parametersao= 6.606(2) Å,co= 5.980(2) Å by ultrasonic pulse superposition and also by phase comparison methods. The values in 1012dyn/cm2arec11= 4.237,c33= 4.900,c44= 1.136,c66= 0.485,c12= 0.703, andc13= 1.495. The estimated uncertainty in the measurements are 0.4% forc11,c33,c44, andc66, and 3% forc12andc13. Wave velocity measurements have also been carried out on a metamict zircon crystal (density 4.531 g/cm3) and it is shown that the velocities are reduced by about one‐fifth the normal values. The compressibility coefficients calculated from the new elastic constants data differ from those determined by diffraction data, though this may be part of a general discrepancy between such measurements.

 

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