Ethene polymerization with modified‐polypropene‐supported highly stable Ziegler catalyst
作者:
Hideharu Mori,
Kouki Ohnishi,
Minoru Terano,
期刊:
Macromolecular Rapid Communications
(WILEY Available online 1996)
卷期:
Volume 17,
issue 1
页码: 25-29
ISSN:1022-1336
年代: 1996
DOI:10.1002/marc.1996.030170104
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractA modified‐polypropene‐supported Ziegler catalyst was prepared using polypropene containing a small amount of poly(7‐methyl‐1,6‐octadiene) as a starting polymer for bromination, lithiation, and reaction with TiCl4. The polymerization of ethene was carried out using the catalyst with Al(C2H5)3in toluene at 60°C up to 100 h. The polymer yield increased linearly with polymerization time, which indicates that the active sites of the modified‐polypropene‐supported Ziegler catalyst are practically stable without deactivation even for 100 h and are able to propagate further polymeriza
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