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Cationic Initiation by Thionyl Chloride/Titanium Tetrachloride. II. Styrene Polymerization

 

作者: HungAnh Nguyen,   Lajos Balogh,   Tibor Kelen,   János Borbély,   Lajos Gulyas,   István Majoros,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1990）
卷期: Volume 27, issue 3  

页码: 247-255

 

ISSN:0022-233X

 

年代: 1990

 

DOI:10.1080/00222339009349550

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The thionyl chloride/titanium tetrachloride combination in methylene chloride solution is found to be a good cationic initiating system for styrene polymerization. the efficiency of the initiation is governed by the amount of titanium chloride used. It was found by the IMA and AMI techniques that the system possesses a partially living character, and the polystyrenes obtained exhibit some stereoregular structure.

 

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