Polymerized Micelle-Protected Platinum Clusters. Preparation and Application to Catalyst for Visible Light-Induced Hydrogen Generation
作者:
Naoki Toshima,
Tadahito Takahashi,
Hidefumi Hirai,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1988)
卷期:
Volume 25,
issue 5-7
页码: 669-686
ISSN:0022-233X
年代: 1988
DOI:10.1080/00222338808053392
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Platinum clusters protected by polymerized micelles were prepared by radical polymerization of unsaturated surfactants which were involved in micelle-protected platinum clusters. The micelle-protected platinum clusters were successfully prepared by photoreduction of hexachloroplatinic acid in water in the presence of unsaturated surfactants. The platinum clusters thus obtained were characterized by electron microscopy and IR and1H-NMR spectroscopies. The average diameter of the platinum particles was about 1 nm by electron microscopy, and the polymerization was confirmed by IR and1H-NMR spectra. The platinum clusters thus obtained proved to be highly active catalysts for visible light-induced hydrogen generation in the system of EDTA/Ru(bpy)32+/MV2+. The polymerized micelle-protected platinum clusters showed higher catalytic activity than the linear polymer-protected one. The catalytic activity was affected by the electric charge of the surfactants in the polymerized micelle-protected platinum clusters. Nonionic polymers were superior to those having anionic and cationic hydrophilic groups from the viewpoint of catalytic activity. The nonionic polymerized micelle forms rigid hydrophobic cores which help charge separation and the formation of a sequential potential field.
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