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Studies on the biosynthesis of the sterpurenes

 

作者: William A. Ayer,   Thomas T. Nakashima,   M. Hossein Saeedi-Ghomi,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1984）
卷期: Volume 62, issue 3  

页码: 531-533

 

ISSN:0008-4042

 

年代: 1984

 

DOI:10.1139/v84-088

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The sterpurenes are a unique group of sesquiterpenes produced by the fungusStereumpurpureum. Biosynthetic studies utilizing [1-13C] and [2-13C] acetate indicate that sterpuric acid (2) and sterpurene-3,12,14-triol (3) are formed from acetate via humulene (5) and the protoilludane cation (6) by one of the paths shown in Scheme 2.

 

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