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[Co(H2O)(HPO4)]·H2O: The Layered Divalent Metal Mono‐hydrogenphosphate Structure

 

作者: Yong‐Kui Shan,   Li‐Yi Dai,   Shu‐Yuan Yu,   Sheng‐Rong Ye,   Ming‐Yuan He,  

 

期刊: Chinese Journal of Chemistry  （WILEY Available online 2002）
卷期: Volume 20, issue 1  

页码: 34-38

 

ISSN:1001-604X

 

年代: 2002

 

DOI:10.1002/cjoc.20020200108

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: hydrothermal reaction;monohydrogenphosphate;hydrogen bonding;structure

 

数据来源: WILEY

 

摘要:

AbstractA new layered divalent metal monohydrogenphosphate [Co(H2O) (HPO4)] · H2O (1) was hydrothermally synthesized from the reaction of CoCl2·6H2O with H3PO4in the presence ofcis‐Pt(NH3)2Cl2and ethylenediamine. The structure features extensive intra‐ and inter‐layer hydrogen bonding among the hydrogenphosphate anion, the coordinated water and the crystallization water. X‐ray crystallographic parameters for 1 are orthorhombicPnma(#62),a= 1.7528(2),b=0.56158(7),c= 0.47867(6) nm,V= 0.47116(9)

 

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