1,2‐Asymmetric induction when grignard reagents are added to of‐aminoketones. I. The influence of different factors and mechanisms of induction
作者:
Antoine Gaset,
Marie‐Thérèse Maurette,
Armand Lattes,
期刊:
Journal of Applied Chemistry and Biotechnology
(WILEY Available online 1975)
卷期:
Volume 25,
issue 1
页码: 1-12
ISSN:0375-9210
年代: 1975
DOI:10.1002/jctb.5020250102
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractThe problem of 1,2‐asymmetric induction has been studied as Grignard reagents were added to α‐aminoketones. The experimental factors have been modified in terms of the hypothesis of an interaction between the amino function and the Grignard reagents. The variations resulting from these changes have enabled an interpretation to be put forth of the phenomena depending on the equilibrium between a dipolar and a cyclic m
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