Selective step‐growth phenol‐aldehyde polymerization, 1. Synthesis, characterization and X‐ray analysis of linear all‐orthooligonuclear phenolic compounds
作者:
Giovanni Casiraghi,
Mara Cornia,
Giovanni Sartori,
Giuseppe Casnati,
Vittorio Bocchi,
Giovanni Dario Andreetti,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 11
页码: 2611-2633
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021831101
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe series of dinuclear to nonanuclear all‐orthomethylene‐bridged oligophenols 2–9 has been synthesized according to a repetitive reaction sequence involving the C‐orthoregiospecific condensation of appropriate phenoxymagnesium precursors with salicyl alcohol or paraformaldehyde. IR, UV, mass,1H and13C NMR characteristics of these oligomers are discussed. X‐ray crystal structures of 2, 3, and 4 are also
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