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LIQUID-LIQUID EXTRACTION OF METAL IONS WITH AMIDO PODANDS

 

作者: Holger Stephan,   Karsten Gloe,   Jörg Beger,   Peter Mühl,  

 

期刊: Solvent Extraction and Ion Exchange  (Taylor Available online 1991)
卷期: Volume 9, issue 3  

页码: 459-469

 

ISSN:0736-6299

 

年代: 1991

 

DOI:10.1080/07366299108918064

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The extraction properties of ami do podands 1 - 3_ have been investigated. The ether dicarboxylic acid diamide i shows a clear preference for the extration of rare earth metal ions Yb(III)-, La(III) and the alkaline-earth metal ions Ca(II), Sr(II) as well. Due to the presence of the carboxylic group the ether dicarboxylic acid monoamide, 2. extracts the ions of the 3d-elements Cu(II), Co(II) and Zn(II), too. High distribution ratios have been obtained mainly for soft and medium-hard transition metal ions with the N-alkyl imino diacetic acid diamide 3_. Under the experimentally chosen conditions, alkali metal ions such as Na(I) and K(I) are practically not extracted by the investigated amido podands.

 

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