LIQUID-LIQUID EXTRACTION OF METAL IONS WITH AMIDO PODANDS
作者:
Holger Stephan,
Karsten Gloe,
Jörg Beger,
Peter Mühl,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1991)
卷期:
Volume 9,
issue 3
页码: 459-469
ISSN:0736-6299
年代: 1991
DOI:10.1080/07366299108918064
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The extraction properties of ami do podands 1 - 3_ have been investigated. The ether dicarboxylic acid diamide i shows a clear preference for the extration of rare earth metal ions Yb(III)-, La(III) and the alkaline-earth metal ions Ca(II), Sr(II) as well. Due to the presence of the carboxylic group the ether dicarboxylic acid monoamide, 2. extracts the ions of the 3d-elements Cu(II), Co(II) and Zn(II), too. High distribution ratios have been obtained mainly for soft and medium-hard transition metal ions with the N-alkyl imino diacetic acid diamide 3_. Under the experimentally chosen conditions, alkali metal ions such as Na(I) and K(I) are practically not extracted by the investigated amido podands.
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