The influence of the interphase on composite properties: Poly(ethylene‐co‐acrylic acid) and poly(methyl vinyl ether‐co‐maleic anhydride) electrodeposited on graphite fibers
作者:
A. S. Crasto,
S. H. Own,
R. V. Subramanian,
期刊:
Polymer Composites
(WILEY Available online 1988)
卷期:
Volume 9,
issue 1
页码: 78-92
ISSN:0272-8397
年代: 1988
DOI:10.1002/pc.750090111
出版商: Society of Plastics Engineers
数据来源: WILEY
摘要:
AbstractThe electrodeposition of saturated copolymers onto carbon fibers is investigated, focusing particular attention on improvement of shear and impact properties of the corresponding composites. Carbon fibers are electrocoated with poly(ethylene‐co‐acrylic acid) and poly(methyl vinyl ether‐co‐maleic anhydride) from aqueous media, and fabricated into epoxy composites. The results of interlaminar shear strength (ILSS) tests, initially employed to assess fibermatrix adhesion, are vitiated by the occurrence of mixed‐mode failure. Interfacial shear strength (IFSS) is hence evaluated by stressing single‐fiber composite specimens to obtain ultimate aspect ratios of the fiber fragments. The data are combined with fiber strengths by a recently developed statistical theory (1) to yield adistributionfor IFSS. Both copolymer interphases improve fiber‐matrix bonding to an extent greater even than that obtained with commercial fiber surface treatment. Good fiber‐matrix adhesion is further apparent from SEM studies of fractured ILSS test specimens. A key to this improved adhesion is the interpenetration of matrix resin and interphase polymer, revealed by electron microprobe analysis (2). Notched Izod impact strength is also increased over uncoated‐fiber composites. These copolymer interphases behave as deformable interlayers, absorbing impact energy and blunting the growing crack tip. Further energy is absorbed in deflecting the crack through a more tortuous path. Simultaneous improvements in impact and shear strengths are thus obtained, which may be further enhanced by optimizing the electrodeposition parameters and the coating thickness. The influence of the interphase on composite properties is better understood from this study, paving the way for refinement in
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