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Solid-State Photoquaternization of Polymer-Bound Pyridine

 

作者: D.M. Snyder,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1989）
卷期: Volume 26, issue 10  

页码: 1437-1450

 

ISSN:0022-233X

 

年代: 1989

 

DOI:10.1080/00222338908052061

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A study of the solid-state ultraviolet photoreaction of polymer-bound pyridine andp-nitrophenoxy groups has shown that pyridinium nitrite crosslinks result from the photoquaternization process. The generation of ionic groups in the crosslinking effectively inhibits the solubility of the irradiated polymer matrix in nonpolar solvents.

 

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