Long-range coupling in cyclohexane fragments
作者:
P.R. Carey,
R. Ditchfield,
期刊:
Molecular Physics
(Taylor Available online 1968)
卷期:
Volume 15,
issue 5
页码: 515-521
ISSN:0026-8976
年代: 1968
DOI:10.1080/00268976800101411
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Couplings over four bonds,4JHH, are discussed for compounds where stereochemistry is thought to be the dominant factor determining their values. A simple MO theory [3, 4] provides calculated coupling constants in agreement with experiment. The form of the theory permits an analysis of the mechanisms responsible for long-range coupling. The approach is generalized to include distorted cyclohexane fragments and these results are presented in a graphical form.
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