Assigning Reactive Excited States in Inorganic Photochemistry
作者:
ArthurW. Adamson,
期刊:
Comments on Inorganic Chemistry
(Taylor Available online 1981)
卷期:
Volume 1,
issue 1
页码: 33-45
ISSN:0260-3594
年代: 1981
DOI:10.1080/02603598108078078
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The matter of assigning reactive excited states in inorganic photochemistry turns out to have complexities as more detailed and more varied information is obtained. Three cases are considered. For Cr(III) ammines there is still much controversy in the assignment of chemical reactivity to doublet and quartet states. In the case of Rh(NH3)5X2+complexes, it may be necessary to invoke three different reactive or emitting ligand-field excited states, while for W(CO)5L species, at least two, including a charge transfer state, are needed.
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