Pressure and temperature dependence of the vibrational excitations of crystalline iodoform
作者:
J. Medina,
W. F. Sherman,
G. R. Wilkinson,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1982)
卷期:
Volume 12,
issue 1
页码: 63-67
ISSN:0377-0486
年代: 1982
DOI:10.1002/jrs.1250120109
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractRaman spectra of single crystals of iodoform have been investigated over the temperature range 10–300 K and under hydrostatic pressure up to 14 kbar. The pressure‐induced shifts in vibrational frequency of many different modes have been used to calculate their respective Gruneisen parameters γ which are found to vary both with the frequency and pressure. They are much greater for the intermolecular modes than for the internal modes. The infrared absorption spectra have also been observed at different temperatures and are used together with the Raman data to obtain dν/dTfor each band. Some new infrared assignments are sugg
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