首页   按字顺浏览 期刊浏览 卷期浏览 Kinetic Network Model for Nonlinear Viscoelastic Properties of Entangled Monodisperse P...
Kinetic Network Model for Nonlinear Viscoelastic Properties of Entangled Monodisperse Polymers. I. Steady‐State Flow

 

作者: D. Soong,   M. Shen,  

 

期刊: Journal of Rheology  (AIP Available online 1981)
卷期: Volume 25, issue 2  

页码: 259-273

 

ISSN:0148-6055

 

年代: 1981

 

DOI:10.1122/1.549644

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

A molecular network theory is proposed to predict the nonlinear flow properties of entangled monodisperse polymers. The rate dependence of the viscosity and normal stress coefficients is attributed to the decrease in entanglement density with increasing shear rate. The probability for the existence of entanglements at a given shear rate is determined by equating the rates of two competing processes, i.e., entanglement creation and disengagement, which in steady flow are in a state of dynamic equilibrium. The entanglement creation process is driven by thermal diffusion and is assumed to be independent of shear rate. The entanglement loss process is caused primarily by the imposed shear and is assumed to be proportional to the shear rate to a powera,a parameter that accounts for the elasticity of the medium. The final equations are algebraically simple and can be easily adapted to most engineering calculations. The theory shows excellent agreement with experimental data on both melts and concentrated solutions.

 

点击下载:  PDF (679KB)



返 回