Studies on Biphase Behaviour of Certain Thermotropic Liquid Crystalline Copolyesters
作者:
R. Nanthini,
R. Balakrishnan,
V. Kannappan,
I.K. Varma,
Neeraj Gupta,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 319,
issue 1
页码: 39-49
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045646
出版商: Taylor & Francis Group
关键词: LC random copolyesters/biphase;discotic behaviour
数据来源: Taylor
摘要:
Four Thermotropic Liquid Crystalline (TLC) random copolyesters were prepared by direct polycondensation of two diols and oxaloyl chloride ino-dichlorobenzene solution. The structures of the repeating units of the synthesised polyesters were examined by FT-IR and PMR spectral data. The thermal transition temperatures were determined by differential scanning calorimetry. The LC behaviour of these polymers were studied by optical polarising microscopy in conjunction with WAXD studies. Three of these polyesters exhibited interesting biphase behaviour. The polyester containing 2,5-ditertiarybutylphenylene rings in the main chain exhibited discotic behaviour.
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