The influence of electron beam irradiation on migrational behaviour of additives present in food packaging material was studied. The migration experiments were carried out on irradiated and non‐irradiated polypropylene pouches containing aqueous food simulating liquids (FSL) for 10 days at 40°C. The controls were irradiated and non‐irradiated pouches without FSL contact. After the contact period, the polypropylene and the FSL were analysed. A comparison between the results obtained by the two analyses showed the migration of three products of antioxidant degradation from the polypropylene into the FSL, and a partial decomposition of these migrants in the FSL.