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Spectroscopic and Structural Studies of Clathrate Compound of Bis(Ethylenediamine)- Diisothiocyanatonickel(II)-Benzene

 

作者: Li Jianmin,   Xu Haitao,   Zhang Yugen,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1999）
卷期: Volume 32, issue 5  

页码: 763-771

 

ISSN:0038-7010

 

年代: 1999

 

DOI:10.1080/00387019909350024

 

出版商: Taylor & Francis Group

 

关键词: electronic absorption spectrum;bis(ethylenediaminde)- diisothiocyanto-nickel(II);ligand field theory;structural studies

 

数据来源: Taylor

 

摘要:

The electronic absorption spectrum of the title crystal of the clathrate compound of [Ni(en)2(NCS)2], C6JH6has been measured. The experimental results are discussed quantitatively with ligand field theory(LFT) and the radial wave function of non-free nickel(II) ion. The calculation values coincide well with the experimental results. In particular, they provide significant correlation between the electronic absorption spectrum and the crystal structure of the compound.

 

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