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Azide Substitution at Mannose Derivatives. A Potential New Route to Glucosamine Derivatives

 

作者: J.N. Vos,   J.H. Van Boom,   C.A.A. van Boeckel,   T. Beetz,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1984）
卷期: Volume 3, issue 1  

页码: 117-124

 

ISSN:0732-8303

 

年代: 1984

 

DOI:10.1080/07328308408057901

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Since the pioneering work of Paulsen et al.1on stereoselective coupling reactions of glucosamine derivatives, the azide function has found general application in carbohydrate chemistry as a nonparticipating masking group for amines. Although excellent results have been reported for the synthesis of α-coupled glucosamine derivatives, the preparation of the required 2-azido-2-deoxy--glucopyranose is often laborious.1c

 

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