We have measured the heat capacity of the fast ion conductor PbSnF4at 10.3 < T < 352 K by adiabatic calorimetry. Our results show anomalous values in theCp,min the region 300 < T < 352 K. These are associated with the α–β crystallographic transition reported at 353 K. Because the upper temperature limit of our cryostat is around 354 K, it was impossible to follow the phase transition to completion. A more subtle anomaly in theCp,mwas detected between 130 and 160 K. Standard molar thermodynamic functions are presented at selected temperatures from 5 to 350 K.