Multiple-quantum filters of arbitrary phases for spin 3/2 nuclei
作者:
DennisJ. Sorce,
Jose Katz,
FerencP. Czegledy,
期刊:
Molecular Physics
(Taylor Available online 1993)
卷期:
Volume 80,
issue 5
页码: 1067-1076
ISSN:0026-8976
年代: 1993
DOI:10.1080/00268979300102881
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The expression for the transverse magnetization for the standard four pulse sequence employed in the construction of a double-quantum filter is derived for arbitrary phase angles. By use of this expression, it is demonstrated that the NMR signal intensity of the corresponding double-quantum filter is maximized when the phases and phase cycling of the pulses employed are determined in accordance with the coherence-transfer pathway formalism. Furthermore, the filtering action of the double-quantum filter is insensitive to perturbations in the phase angles of up to 15° around these values. For these variations in phase angles, the transverse magnetization of the double-quantum filter signal decreases by at most 10%. This decrease in signal intensity is due solely to the functional dependence of the transverse magnetization on the phase angles and not due to the breakthrough of other coherences.
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