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Multiple-quantum filters of arbitrary phases for spin 3/2 nuclei

 

作者: DennisJ. Sorce,   Jose Katz,   FerencP. Czegledy,  

 

期刊: Molecular Physics  (Taylor Available online 1993)
卷期: Volume 80, issue 5  

页码: 1067-1076

 

ISSN:0026-8976

 

年代: 1993

 

DOI:10.1080/00268979300102881

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The expression for the transverse magnetization for the standard four pulse sequence employed in the construction of a double-quantum filter is derived for arbitrary phase angles. By use of this expression, it is demonstrated that the NMR signal intensity of the corresponding double-quantum filter is maximized when the phases and phase cycling of the pulses employed are determined in accordance with the coherence-transfer pathway formalism. Furthermore, the filtering action of the double-quantum filter is insensitive to perturbations in the phase angles of up to 15° around these values. For these variations in phase angles, the transverse magnetization of the double-quantum filter signal decreases by at most 10%. This decrease in signal intensity is due solely to the functional dependence of the transverse magnetization on the phase angles and not due to the breakthrough of other coherences.

 

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