Grafting of Maleic Anhydride onto Acrylonitrile-Butadiene-Styrene Terpolymer: Synthesis and Characterization
作者:
B.Madhusudhan Rao,
P.Raghunath Rao,
B. Sreenivasulu,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1999)
卷期:
Volume 38,
issue 5
页码: 967-977
ISSN:0360-2559
年代: 1999
DOI:10.1080/03602559909351625
出版商: Taylor & Francis Group
关键词: Graft copolymerization;ABS;Maleic anhydride;Grafting site.
数据来源: Taylor
摘要:
The graft copolymerization of maleic anhydride (MAH) onto a acryloni-trile-butadiene-styrene (ABS) terpolymer was carried out using benzoyl peroxide (BPO) as an initiator and toluene as a solvent. The effects of various parameters such as monomer concentration, initiator concentration, reaction time, and temperature on graft yield were studied. Addition occurs in the butadiene region of the polymer, either by the loss of vinylic hydrogen and subsequent radical formation and addition of monomer or by addition to the double bond. The graft copolymers were characterized by infrared, thermogravirnetric analysis, and differential scanning calorimetry. Thermal stability was improved andTgwas increased.
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